Transition Metal Complexes of Low Valent Gallium Species
نویسندگان
چکیده
منابع مشابه
Cationic cluster formation versus disproportionation of low-valent indium and gallium complexes of 2,2'-bipyridine
Group 13 M(I) compounds often disproportionate into M(0) and M(III). Here, however, we show that the reaction of the M(I) salt of the weakly coordinating alkoxyaluminate [Ga(I)(C6H5F)2](+)[Al(OR(F))4](-) (R(F)=C(CF3)3) with 2,2'-bipyridine (bipy) yields the paramagnetic and distorted octahedral [Ga(bipy)3](2+)(•){[Al(OR(F))4](-)}2 complex salt. While the latter appears to be a Ga(II) compound, ...
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ژورنال
عنوان ژورنال: Bulletin of Japan Society of Coordination Chemistry
سال: 2007
ISSN: 1882-6954,1883-1737
DOI: 10.4019/bjscc.50.18